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مطالعه ي کاني شناسي و ژئوشيمي کانسار آهن شهرک يک، شرق تکاب

تعداد 115صفحه در فایل word

کارشناسي ارشد در رشته زمين­شناسي گرايش زمين­شناسي اقتصادي

 

 

 

 

مطالعه ي کاني شناسي و ژئوشيمي کانسار آهن شهرک يک، شرق تکاب

 

 

 

چكيده:

کانسار آهن شهرک در شرق تکاب ودر زون اروميه-دختر واقع است. واحدهاي رخنمون يافته در منطقه شامل آندزيت، تراکي آندزيت، ريوداسيت، توناليت، کوارتز مونزونيت و سنگ هاي آهکي است.توده آذرين در سنگ هاي فوق نفوذ کرده و ضمن ايجاد دگرگوني مجاورتي و دگرساني، به کمک سيال هاي گرمابي، آهن را از اين منجموعه جدا نموده و با تغيير شرايط فيزيکوشيميايي، آن را درون آهک و در همبري با توده آذرين،متمرکز کرده است. محدود بودن رخداد آهن به همبري با توده آذرين و در کربنات ها و وجود کاني شناسي اسکارن ، گواه بر تشکيل اسکارن آهن است. مهم ترين دگرساني سنگ هاي منطقه، دگرساني پروپليتيک است.  مطابق نتايج آناليزهاي ژئوشيميايي، سنگ هاي منطقه: کالک آلکالن، متاآلومين و وابسته به ماگماتيسم تيپ I هستند. نتايج آناليز EPMA بر روي بلور گارنت نشان داد که اين بلورها  متعق به سري گرانديت ( گراسولار- آندراديت ) و ناحيه بندي در آن ها نوساني و پيچيده است. چگونگي تغيير عناصر Al و Fe از مرکز به سمت حاشيه گوياي آن است که نوسان از مرکز تا حاشيه ي بلور در ميزان دو عضو انتهايي گراسولار و آندراديت در سري محلول جامد گرانديت رخ داده است، لذا ساختمان منطقه اي گارنت ها هنگام رشد بلور به وجود آمده و فرآين نشر در تشکيل آن ها نقشي نداشته است. با اين وجود ترکيب گارنت در حوالي برخي از شکستگي ها متفاوت بوده  و اين تفاوت در تصوير BSE کاني ديده مي شود. لذا ساختمان منطقه اي ايجاد شده در اثر نشت آبگون ها در کاني به صورت  به صورت موضعي بهم خورده است. منطقه ي مورد مطالعه بر اساس مشاهدات کاني شناسي ( گارنت، اپيدوت وعدم وجود پيروتيت ) و آناليزهاي ژئوشيميايي : 1) اسکارن کلسيمي است 2) در شرايط اکسيداسيون تشکيل شده است. 3)دماي تشکيل آن کمتر از ˚C 550 است.

واژه­هاي کليدي: شهرک-1، آناليز شيميايي، گارنت، ساختمان بندي نوساني، اسکارن.

 

دسته: , برچسب: , , , ,

فهرست مطالب

فصل اول: کليات

1-1 مقدمه: 3

1-2 شرايطآبوهواييوپوششگياهيوجغرافيايانساني: 3

1-3 کلياتآهن: 3

هدفازمطالعه: 12

1-4 روشکار: 12

1-5 تاريخچه‌يمطالعاتزمينشناسيمنطقه: 13

1-6 شرايطآبوهواييوپوششگياهيوجغرافيايانساني: 14

فصل دوم: زمين شناسي و پتروگرافي

2-1- زمينشناسيناحيه‌اي: 17

2- 1-1- فعاليت‌هايآتشفشانيدرزوناروميه–دختر: 18

2- 1- 2- ماگماتيسمزوناروميه- دختر: 20

2- 1- 3- کانيسازيزوناروميه–دختر: 22

2-1- 4- زمينشناسيمنطقهتکاب: 24

2- 1-5- چينه شناسي منطقه تکاب: 25

2-1-6- سنگ شناسي منطقه تکاب: 25

2- 1-7- وضعيت ساختاري منطقه تکاب: 28

2- 1-8- فاز‌هاي کوهزايي منطقه تکاب: 29

2- 1-9- ماگماتيسم منطقه تکاب: 31

2- 1-10- فازهاي کاني سازي منطقه تکاب: 32

2- 2- زمينشناسي منطقه موردمطالعه: 33

2- 3- پتروگرافي سنگ‌هاي آذرين آتشفشاني: 35

2- 3- 1- تراکي آندزيت: 35

2- 3- 2- ريوداسيت: 35

2- 4- پتروگرافي سنگ‌هاي آذرين نفوذي: 36

2- 4- 1- کوارتزمونزونيت پورفيري: 37

2- 4–2 توناليت–کوارتزديوريت: 37

2- 5- دگرساني: 38

2- 5- 1- دگرساني رسي: 38

2-5-2- دگرساني پروپليتيک: 39

2- 6- اسکارن زايي: 40

فصل سوم: کاني شناسي و کانه نگاري

3- 1- کانيشناسي کاني‌هاي باطله‌ ي کانسارآهن شهرک -1: 45

3-1- 1- اکتينوليت – ترموليت: 45

3- 1- 2- اپيدوت: 46

3- 1- 3- گارنت: 46

3- 1- 4- وزوويانيت: 47

3- 1- 5- کلريت: 48

3- 1- 6- کلسيت: 48

3- 2- کاني شناسي کاني‌هاي فلزي کانسارآهن شهرک -1: 49

3- 2- 1-  مگنتيت: 49

3- 2- 2- هماتيت: 51

3- 2- 3- پيريت: 51

3- 2- 4- گوتيت: 52

3- 2- 5- کالکوپيريت: 52

3- 2- 6- مالاکيتوآزوريت: 52

3- 3- پاراژنزوتواليپاراژنزي: 53

ژئوشيميايي.. 56

فصل چهارم: مطالعات ژئوشيميايي

4-1 مقدمه: 58

4-2-: طبقه بندي سنگ‌هاي پلوتونيک: 58

4- 2- 1: طبقه بندي (1994)ميدلموست: 58

4- 2 – 2 نمودار‌هاي کاتيوني: 58

4-3- نمودارهاي رده بندي سنگ‌هاي آتشفشاني: 59

4- 3- 1- نمودارعناصرکمياب وينچستروفلويد (1977 و 1978): 59

4- 3- 2- نمودارمارتين (2010): 60

4- 4- ترکيب شيمياي يسنگ‌هاي آذرين وتحولات ماگمايي: 60

4- 4 -1 تعيين سري ماگمايي: 60

4- 4 -2 بررسي درج هاشباعي ازآلومين: 61

4-5 بررسي جايگاه تکتونيکي توده‌ي گرانيتوئيد يمنطقه موردمطالعه: 62

4-5-1- نمودارپيرس وهمکاران (1984): 62

4-6  نمودارهاي تغييرات شيميايي (Harker diagrams): 62

4-6-1 نمودارتغييرات شيميايي براي عناصراصلي: 62

4-6-2 نمودارتغييرات شيميايي براي عناصر فرعي: 63

4-7-تعيين نوع گرانيتوئيدهاي منطقه‌ي موردمطالعه: 64

4-8- تعيين منشأ گرانيتوئيدهاي منطقه‌ي موردمطالعه وفرآيندهايمؤثردرتشکيلآن‌ها: Error! Bookmark not defined.

4- 9 ژئوشيمي عناصر نادرخاکي: 66

4-9-1- بررسي نمودارعنکبوتي بهنجارشده باPrimitiv mantle: 66

4-9-2- بررسي نمودارعنکبوتي بهنجارشده باکندريت: 67

4-10- مقايسه ترکيب سنگ‌هاي نفوذي کانسار شهرک -1 باتوده‌هاي نفوذي همراه بااسکارن‌هاي جهان: 68

4-10-1- عناصراصلي: 69

4-10-2- عناصرجزئي: 69

4-11- تعيين منشأ سيالاتکانسارساز: Error! Bookmark not defined.

4-12- ژئوشيميگارنت: 70

4-12- 1- بررسي ترکيب شيميايي گارنت: 71

4-12-2- بررسي نوع ساختمان منطقه‌اي ( زونينگ ) درگارنت: 74

4-12-3- عوامل تشکيل ساختمان منطقه‌اي رشدي نوساني: 74

4-13- تکامل فيزيکوشيميايي درشکل گيري زون‌هاي اسکارني: 78

نتيجه گيري: 84

پيشنهادات: 90

فهرست منابع فارسي: 94

فهرست جدول

جدول 3-1: پاراژنزمنطقه موردمطالعه. 54

جدول 4-1: جدول طبقه بندي سنگ‌ها براساس ميزان آلوميناي موجود درآن‌ها طبق نمودار دوبون ولوفرت (1983). 59

فهرست اشکال

شکل ( 1 -1 ): راه‌هايهايارتباطيمعدنسنگآهنشهرکواقعدرشرقتکاب… 14

شکل (2 -1 ): نقشه 250000:1 تکاب… 17

شکل ( 2 – 2 ): تقسيمبنديتکتونيکيچهارگوشتکاب… 28

شکل ( 2 – 3 ): نقشه 1000: 1 کانسارشهرک- 1. 34

تصوير 2-4: الفوب) تصاويرمقاطعميکروسکوپيازتراکيآندزيتبابافتپورفيري. (فنوکريست‌هايپيروکسنوپلاژيوکلازدرزمينه‌ايازکوارتزدانهريزقرارگرفتهاند. ج) تصاويرماکروسکوپيازتراکيآندزيتها ( ديدبهسمتجنوبشرق). علائماختصاري: پيروکسن (Px)،پلاژيوکلاز (Pl)،آلکاليفلدسپار (Afs)،کوارتز (Qz) 36

تصوير 2-5:  الف( بافتغرباليدرکوارتزهايموجوددرريوداسيت. ب(بافتپورفيري (فنوکريست‌هايپلاژيوکلازوکوارتزدرزمينه‌ايازميکروليت. ج(تصويرماکروسکوپيازريوداسيت‌هايدرمنطقه‌يموردمطالعه. د(آپاتيت‌هايتيغه‌ايکهبهعنوانکانيفرعيدرريوداسيت‌هامشاهدهمي‌شوند.علائماختصاري: پلاژيوکلاز (Pl)،آپاتيت (Ap)،کوارتز (Qz) 36

تصوير 2-6: الف)  مقطعميکروسکوپيکهبافتگلومروپورفيريدرکوارتزمونزونيت‌هارانشانمي‌دهد. (فنوکريست‌هايهورنبلندبهصورتتجمعاتخوشهماننددرزمينه‌يازکاني‌هايدانهريزقرارگرفتهاند. ب) مقطعميکروسکوپيکهبافتاينترگرانولاررادرکوارتزمونزونيتنشانمي‌دهد ( فواصلبيندرشتبلورهايپلاژيوکلازتوسطکاني‌هايماقيکومقداربسيارکميکوارتزاشغالشدهاست. جتصويريازنمونهدستيمربوبهکوارتزمونزونيت. د)  بلورهايپاژيوکلازکهبافتمنطقهبنديرانشانمي‌دهند. علائماختصاري: پلاژيوکلاز (Pl)،هورنبلند (Hbl)،کوارتز (Qz) 38

شکل ( 2 –7)  تصاويريازمقاطععرضيمربوطبهکانسارشهرک- 1) 38

تصوير 2-8: الف) کلريت‌هايموجوددرزوندگرسانيپروپليتيک ( کلريتها،حاصلتأثيرمحلول‌هايهيدروترماليبررويکاني‌هايمافيکموجوددرسنگمانندآمفيبول‌هاهستند. ب) اپيدوتبهعنوانيکيازکاني‌هايشاخصدگرسانيپروپليتيکدرمنطقه‌يموردمطالعه. ج) تبديلپلاژيوکلازبهسرسيت ( يکيازمحصولاتدگرسانيرسي). د) کانياسفنکهمحصولدگرسانيفلدسپات‌هامي‌باشدوشاخصدگرسانيپروپليتيکاستعلائماختصاري: پلاژيوکلاز (.Pl)،اپيدوت (Ep)،کلريت (Chl)،سرسيت (Ser)،اسفن (Spn) 39

تصوير 3-1:  محدوده‌يپايداريکانيوزوويانيت… 48

تصوير3-2:  الف) تصاويرميکروسکوپيازبلورهاياپيدوتوکلسيتکهبهعنوانمهمترينکاني‌هايباطلههمراهماده‌يمعدنيمشاهدهميشوند. ب) تصاويرميکروسکوپيازبلورهايگارنتبابافتکاتاکلاستيکدرزمينه‌ايازکلسيتج: تصويرماکروسکوپيازآمفيبولهايموجوددرزونآمفيبولاسکارن. د:تصاويرميکروسکوپيازبلورهايدستهجاروييفرواکتينوليتعلائماختصاري: کلسيت (.Cal)،اپيدوت (Ep)،گارنت (Grt)،اکتينوليت (Act). 49

تصوير 3-3: الفوب) رگچه‌هايميکروسکوپيکلسيتيدرکانسنگ (محلول‌هايغنيازCO2درزوشکاف‌ها‌يکانسنگراپرکردهاند. ج) تصويريازدرشتبلورهايآهکدرمنطقه‌يموردمطالعه. د) تصويرميکروسکوپيازسنگهايآذرينيکهآهکيشدهاند. علائماختصاري: پيريت (Py)،مگنتيت (Mag)،آلکاليفلدسپار (Afs)،کلسيت (Cal)،کوارتز (Qz) 49

تصوير 3-4: تصاويرمربوطبهساختوبافتمگنتيتدرمنطقه‌يموردمطالعه. الفود) مگنتيتبافرمبلوريکامل. ب) مگنتيت‌هايتوده‌ايوبيشکلکهغالبأمگنتيت‌هايمنطقهساختتوده‌ايدارند. ج) مگنتيت‌هاييباساختنواريريتميک ( باندهايروشنکلسيتوباندهايتيرهگارنتومگنتيتهستند). 50

تصوير 3-5: تصاويرميکروسکوپيمربوطبهانواعبلورهايمگنتيت،الفوبمگنتيت‌هاييباشکلبلوريتيغهاي،جودمگنتيتباشکلبلوريخودشکل (يوهدرال) درزمينه‌ايازکلسيت. علائماختصاري: مگنتيت (Mag)،آمفيبول(Amp)،کلسيت(Cal)، 51

تصوير 3-6: مقاطعميکروسکوپيکهانواعبافتدرمگنتيت‌ها‌يمنطقه‌يموردمطالعهرانشانمي‌دهند. الف) بافتتوده‌ايدرمگنتيت،ب) بافتپراکنده،ج) بافتکرمخورده،د) بافتکاتاکلاستيک،وو‌ي) تصاويرماکروسکوپيازمگنتيت. علائماختصاري: آمفيبول (Amp)،کلسيت (Cal)،مگنتيت (Mag)،پيريت (Py) 51

تصوير 3-7: تصاويرميکروسکوپيوماکروسکوپيمربوطبهپيريت. الف) بافتکرمخوردگيدرپيريت،ب) بافتبرشي،ج) تصويرمربوطبهنمونهدستيپيريتهايمنطقهموردمطالعه.علائماختصاري:کلسيت (Cal)،مگنتيت (Mag)،پيريت (Py) 52

تصوير 3-8: تصاويرميکروسکوپيمربوطبهانواعبافتدرهماتيت‌هايمنطقه‌يموردمطالعه،الفودبافتسوزنيدراسپکولاريت ( درامتدادسطوحشکستگيهماتيتجانشينمگنتيتشدهاستوبهتدريجبلورهايتيغه‌اياسپکولاريتدرحالتوسعهمي‌باشند) ب) مارتيتيشدنمگنتيت‌هارانشانمي‌دهد. ج) بافتجزيره‌ايپيريتهاييکهبهصورتپراکندهدرمگنتيت‌هايهماتيتيشدهحضوردارند. حو‌ي) تصاويرماکروسکوپيمربوطبهليمونيتوهماتيت‌هايمنطقه‌يموردمطالعه. 53

تصوير 4-1: طبقبنديسنگ‌هايآذريننفوذيمنطقهبراساسنمودارميدلموست (1994). 58

تصوير4- 2: طبقهبنديشيمياييسنگ‌هايمنطقه‌يموردمطالعهبراساسمقاديرکاتيوني. 59

تصوير 4- 3: طبقهبنديسنگ‌هايآتشفشانيمنطقه‌يموردمطالعهبااستفادهازنمودارهايمارتين (2010) ووينچستروفلويد (1977). 60

تصوير 4- 4: تعيينسريماگماييسنگ‌هايمنطقه‌يموردمطالعهبراساسنمودارايرواينوباراگار (1971). 61

4-5: بررسيدرجه‌ياشباعيازآلومينيومبرايسنگ‌هايمنطقه‌يموردمطالعهبراساسنمودارشاند (1943). 61

تصوير 4-6: تعيينخواستگاهتکتونيکيسنگ‌هايمنطقه‌يموردمطالعهبااستفادهازنمودارپيرسوهمکاران (1984). 62

تصوير 4-7: نمايشتغييراتاکسيدهايعناصراصلينسبتبهسيليسبرايسنگ‌هايمنطقه‌يموردمطالعه. 64

تصوير 4-8: نمايشتغييراتاکسيدهايعناصرفرعينسبتبهسيليسبرايسنگ‌هايمنطقه‌يموردمطالعه. 64

تصوير4-9: تعييننوعگرانيتوئيدهايمنطقه‌يموردمطالعهبااستفادهازنمودارهايچپلووايت (2001) وکلينزوهمکاران (1980). 65

تصوير 4-10: تعيينفرآيندهايموثردرتحولاتماگمايمنشأسنگ‌هايتشکيلدهنده‌يمنطقه‌يموردمطالعهبااستفادهازنمودارعبداللهوهمکاران (1997). Error! Bookmark not defined.

تصوير 4-11: نمودارعناصرناسازگار- ناسازگاربهمنظوربررسيفرآيندهايمؤثردرتحولماگمايمنطقه‌يموردمطالعه. 66

تصوير4-12: نمودارعناصرکمياببههنجارشدهبهPrimitive mantle. : 67

تصوير4-13: الف: نمودارعناصرخاکيبههنجارشدهباکندريتبراساسباينتون (1984) وببراساسناکامورا (1974). 68

تصوير 4-14:  نمودارAFMبرايتوده‌ينفوذيمنطقهومقايسه‌يآنباسايرتوده‌هاينفوذيهمراهاسکارنها 69

تصوير4-15: بررسيميزانعناصرجزييتوده‌هايهاينفوذيهمراهاسکارنکانسارهاياسکارنمختلف;الفRb/Sr نسبتبهZr،بRb-Zr (مينرت، 1992). 70

تصوير 4-16: تعيينمنشأسيالاتکانسارسازبااستفادهازنمودارکاتو (1999). Error! Bookmark not defined.

تصوير4-17: نتابجتغييراتدرصدوزنياکسيدهايCaO،SiO2،FeOوAl2O3درزونينگبلورگارنت. 72

تصوير4-18: نمودارتوزيعترکيبشيمياييگارنت‌هايمنطقه‌يموردمطالعهومقايسه‌يآنباترکيبگارنت‌هاياسکارنسايرنقاطدنيابراساسمينرت 1989. 73

تصوير4-19: تصاويرمربوطبهنمونه‌يدستيومقاطعميکروسکوپيازگارنتدرمنطقه‌يموردمطالعه. الف) نمونه‌يدستيازگارنتدرزمينه‌ايازکلسيتومگنتيتدرواحدهاياسکارنيمنطقه‌يموردمطالعه. ب) تصويرمغزه‌يحفاريکهگارنتوکلسيترادرکنارکاني‌هايشاخصاسکارنيماننداپيدوتنشانمي‌دهد ( مغزه‌يحفارياززونگارنتاسکارنانتخابشدهاست). جتصاويرمربوطبهBSEگارنت (ساختمانبنديرشدينوسانيدرمناطقيکهشکستگيوجودداردازبينرفتهاست.لازمبهذکراستکهباندهايروشنآندراديتوباندهايتيرهگراسولارهستند. دتبديلشدگيگارنتبهوزوويانيت.علائماختصاري: کوارتز (Qz)،کلسيت (Cal)،گارنت (Grt)،وزوويانيت (Vs) 76

تصوير 4-20: محدوده‌يپايداريگارنتنوعآندراديتبراساسفوگاسيته‌ياکسيژنوسولفيد. 77

تصوير 4-21: نمودارروابطفازيT- Log f O2درسامانه‌يSi- Ca- Fe-C- O-H (اينودي،1982). 78

تصوير 4-22: نمودارT-XCO2درفشار 500 بارکهمحدوده‌يپايداريگارنتنوعگراسولاررانشانمي‌دهد ( ترسيوفورست، 1991). علائماختصاري: آنورتيت (An)،کلسيت ((Cal،کوارتز (Qz)،گراسولار (Grs)،گوتيت (Gh)،ولاستونيت (Wo). 79

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