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دانلود پروژه: زمین­شناسی، کانی­شناسی، ژئوشیمی و ارزیابی کانی­های گروه فیروزه در معدن باغو -دامغان و مقایسه آن با سایر فیروزه­ها

تعداد119صفحه در فایل word

کارشناسی ارشد در رشته

زمین­شناسی ( گرایش اقتصادی)

زمین­شناسی، کانی­شناسی، ژئوشیمی و ارزیابی کانی­های گروه فیروزه در معدن باغو -دامغان و مقایسه آن با سایر فیروزه­ها

فیروزه یکی از قدیمی­ترین گوهرسنگ­های شناخته شده در جهان است و استفاده از آن قدمتی نزدیک به 10000سال دارد. از دیدگاه ساختاری معدن مس – طلا- فیروزه باغو (کوه زر) دامغان بخشی از کمان آتشفشانی ترود – چاه­شیرین به سن ائوسن است. این معدن در زون ایران مرکزی و سنگ­های آتشفشانی داسیتی به سن ائوسن پسین – الیگوسن آغازی قرار گرفته است. فیروزه­های این معدن بصورت رگه، رگچهو افشان تشکیل شده است و دارای تغییرات رنگ­شناختی از آبی روشن، آبی آسمانی تا سبز مایل به آبی تغییر می­کند.

به منظور بررسی ویژگی­های زمین­شناسی و ژئوشیمیایی فیروزه در معدن باغو، مطالعات صحرایی، میکروسکوپی، پتروگرافی، زمین شیمیایی انجام شد. مطالعات میکروسکوپی بر روی مقاطع نازک و صیقلی وجود دو فاز کانه­زایی اولیه و ثانویه را نشان داد. پیریت همراه با فازهای جزئی کالکوپیریت و طلا در مراحل اولیه و اکسیدهای آهن مانند هماتیت و ژاروسیت، پیریت،کوپریت، تورمالین در مرحله ثانویه تشکیل شده است. فیروزه به عنوان آخرین فاز کانه­زایی در زون آرژیلیک پیشرفته در کنار آلونیت تشکیل شده است و کانه­زایی­های پیشین را قطع کرده است.

دستیابی به معیاری برای یکسان سازی ارزش­گذاری فیروزه در بازار داخلی  از روش TGIبراساس تغییرات عوامل گوناگون استفاده شده است.اندیس TGI یا Turquoise Grading Indexروش کمی و کیفی برای درجه­بندی و ارزیابی فیروزه بوده و براساس هشت عامل سختی، رنگ، پاکی، طرح زمینه، ترکیب زمینه، بهسازی، تراش و اندازه فیروزه ارزیابی و با توجه به توازن عوامل گوناگون امتیازبندی شده و امتیاز نهایی ارزش فیروزه را براساس قیراط مشخص می­شود.

کلید واژه­ها : فیروزه، فیروزه باغو، روش TGI، درجه­بندی فیروزه، ارزیابی فیروزه

دسته: , برچسب: , , , ,

عنوان                                                                                                                                             صفحه

فصل اول : کلیات

  • مقدمه ………………………………………………………………………………………………………………………………………………………………. 2

  • خصوصیاتفیزیکیوشیمیاییفیروزه ……………………………………………………………………………………………………………. 3

  • کانی­هایگروهفیروزه ……………………………………………………………………………………………………………………………………… 5

  • انواعفیروزه ………………………………………………………………………………………………………………………………………………………. 6

1-4-1- فيروزهعجمى ………………………………………………………………………………………………………………………………………………. 6

1-4-2- فیروزهشجری ……………………………………………………………………………………………………………………………………………… 6

1-4-3-  انواع دیگر فیروزه ………………………………………………………………………………………………………………………………………… 6

  • تاريخچهفيروزهدرجهانوايران ……………………………………………………………………………………………………………………. 7

1-5-1- تاریخچه فیروزه در ایران …………………………………………………………………………………………………………………………….. 7

      1-5-1-1- پیش از تاریخ ………………………………………………………………………………………………………………………………………….. 7

      1-5-1-2- دوران تاریخی …………………………………………………………………………………………………………………………………………..8

      1-5-1-3- دوران اسلامی …………………………………………………………………………………………………………………………………………. 8

1-5-2- تاریخچه فیروزه در مصر ……………………………………………………………………………………………………………………………… 8

1-5-3- تاریخچه فیروزه در چین ……………………………………………………………………………………………………………………………… 9

1-5-4- تاریخچه فیروزه در آمریکا …………………………………………………………………………………………………………………………… 9

  • کانی­هایشبهفیروزه …………………………………………………………………………………………………………………………………….. 10

  • ذخايرجهاني …………………………………………………………………………………………………………………………………………………. 12

1-7-1- ایران ………………………………………………………………………………………………………………………………………………………….. 12

1-7-1-1- فیروزهنیشابور …………………………………………………………………………………………………………………………………….. 12

1-7-1-2- فیروزهباغو (کوهزر) …………………………………………………………………………………………………………………………… 13

1-7-1-3- فیروزه کرمان ( میدوک) ……………………………………………………………………………………………………………………… 13

1-7-2- مصر …………………………………………………………………………………………………………………………………………………………… 13

1-7-3- چین ………………………………………………………………………………………………………………………………………………………….. 13

1-7-4- ایالاتمتحدهآمریکا …………………………………………………………………………………………………………………………………. 14

1-7-4-1-Ajax………………………………………………………………………………………………………………………………………………… 14

1-7-4-2-  Bisbee ………………………………………………………………………………………………………………………………………………. 15

1-7-4-3- Cerrillos ……………………………………………………………………………………………………………………………………………. 15

1-7-4-4-Sleeping Beauty …………………………………………………………………………………………………………………………….. 15

1-7-5- سایرکشورها …………………………………………………………………………………………………………………………………………….. 16

  • فیروزه و خرافات ……………………………………………………………………………………………………………………………………………. 16

  • تجارت جهانی فیروزه …………………………………………………………………………………………………………………………………….. 17

  • صادرات فیروزه در ایران ……………………………………………………………………………………………………………………………… 17

فصل دوم : زمین­شناسی منطقه

2-1- موقعیت جغرافیایی منطقه …………………………………………………………………………………………………………………………….. 20

2-2- راه­های ارتباطی منطقه ………………………………………………………………………………………………………………………………….. 20

2-3- زمین شناسی عمومی ترود ……………………………………………………………………………………………………………………………. 22

2-4- ماگماتیسم در ایران مرکزی ………………………………………………………………………………………………………………………….. 23

2-5- چینه شناسی کلی ناحیه ترود ………………………………………………………………………………………………………………………. 23

2-5-1- واحد های دگرگونی قبل از اردوویسین ……………………………………………………………………………………………………. 24

2-5-2- واحدهای پالئوزوئیک ………………………………………………………………………………………………………………………………… 24

2-5-3- واحد­های مزوزوئیک ………………………………………………………………………………………………………………………………….. 24

2-5-3-1- تریاس و  ژوراسیک ………………………………………………………………………………………………………………………………. 24

2-5-3-2- کرتاسه ………………………………………………………………………………………………………………………………………………….. 24

2-5-4- واحدهای سنوزئیک …………………………………………………………………………………………………………………………………… 25

2-5-4-1- واحدهای ائوسن ……………………………………………………………………………………………………………………………………. 25

2-5-4-2- واحدهای الیگو – میوسن ……………………………………………………………………………………………………………………… 25

2-5-4-3- واحدهای پلیو – کواترنری …………………………………………………………………………………………………………………… 25

2-6- سنگ­های نفوذی …………………………………………………………………………………………………………………………………………… 25

2-7- تکتونیک ناحیه ترود ……………………………………………………………………………………………………………………………………… 25

2-8- زمین شناسی منطقه معدنی باغو ………………………………………………………………………………………………………………….. 27

2-9- چینه شناسی منطقه باغو ……………………………………………………………………………………………………………………………… 29

2-9-1- رسوبات آبرفتی پای­کوه، دشت و آبرفت­های جوان کواترنری ………………………………………………………………….. 30

2-9-2- کنگلومرا و تراس های آبرفتی (پلیو – کواترنری) …………………………………………………………………………………….. 30

2-9-3- توف و خاکستر آتشفشانی و مارن های گچ­دار (میوسن- پلیوسن) …………………………………………………………. 30

2-9-4- دایک های منطقه(اولیگوسن – میوسن) ………………………………………………………………………………………………….. 30

2-9-5- توده­های نفوذی نیمه عمیق (ائوسن پسین – اولیگوسن) ………………………………………………………………………… 33

2-9-5-1-  توده نفوذی نیمه عمیق میکرودیوریتی ……………………………………………………………………………………………… 33

2-9- 5-2- توده نفوذی گرانودیوریتی …………………………………………………………………………………………………………………… 33

2-9-6- واحدهای ولکانو – پیروکلاستیک(ائوسن میانی) ……………………………………………………………………………………… 34

2-10- تکتونیک در محدوده باغو …………………………………………………………………………………………………………………………… 34

2-10-1- روند شمال شرق – جنوب غرب با امتداد N55- 70E ………………………………………………………………………… 34

2-11- گسل­های موجود در منطقه ………………………………………………………………………………………………………………………… 34

2-11-1- گسل باغو ……………………………………………………………………………………………………………………………………………….. 34

2-12- مطالعات پیشین ………………………………………………………………………………………………………………………………………….. 34

فصل سوم : مطالعات پتروگرافی

3-1- دگرسانی در منطقه ……………………………………………………………………………………………………………………………………….. 38

3-1-1- دگرساني پروپيليتيك ……………………………………………………………………………………………………………………………….. 38

3-1-2- دگرساني آرژيليك …………………………………………………………………………………………………………………………………….. 38

3-1-3- آلونيتي شدن …………………………………………………………………………………………………………………………………………….. 39

3-1-4- دگرساني  سرسيتيك ……………………………………………………………………………………………………………………………….. 39

3-1-5- دگرساني پتاسيك …………………………………………………………………………………………………………………………………….. 39

3-1-6 – سيليسي شدن …………………………………………………………………………………………………………………………………………. 40

3-2- شناسایی سنگ میزبان ………………………………………………………………………………………………………………………………….. 40

3-3- مراحل کانه­زایی …………………………………………………………………………………………………………………………………………….. 41

3-3-1- کانه­زایی در زون اولیه ………………………………………………………………………………………………………………………………. 41

3-3-1-2- کالکوپیریت …………………………………………………………………………………………………………………………………………… 41

3-3-1-3- طلا ……………………………………………………………………………………………………………………………………………………….. 41

3-3-2- کانه­زایی در زون ثانویه ……………………………………………………………………………………………………………………………… 41

3-3-2-1- پیریت …………………………………………………………………………………………………………………………………………………… 41

3-3-2-2- اکسیدهای آهن ……………………………………………………………………………………………………………………………………. 41

3-3-2-3- کوپریت …………………………………………………………………………………………………………………………………………………. 42

3-3-2-4- تورمالین ……………………………………………………………………………………………………………………………………………….. 42

3-3-2-5- فیروزه …………………………………………………………………………………………………………………………………………………… 45

3-4- پراش پرتو X(XRD)………………………………………………………………………………………………………………………………….. 47

فصل چهارم :  بررسی­های زمین­شیمی

4-1- مقدمه …………………………………………………………………………………………………………………………………………………………….. 51

4-2- میکروسکوپ الکترونی روبشی (SEM) ………………………………………………………………………………………………………. 51

4-3- طیف سنجی جرمی پلاسمای جفت دیده القائی(ICP-MS)…………………………………………………………………….. 54

4-3-1- عناصر متحرک و غیرمتحرک در فیروزه و سنگ میزبان …………………………………………………………………………. 54

4-3-2-  عناصر کمیاب خاکی ………………………………………………………………………………………………………………………………….55

4-3-2-1- ژئوشیمی عناصر کمیاب خاکی ……………………………………………………………………………………………………………. 55

4-3-2-2-  پراکندگی عناصر کمیاب خاکی در منطقه …………………………………………………………………………………………. 57

4-3-3- شناسایی سنگ میزبان ……………………………………………………………………………………………………………………………… 58

فصل پنجم : ارزیابی فیروزه

5-1- ارزیابی فیروزه ………………………………………………………………………………………………………………………………………………… 63

5-1-1- وزن ……………………………………………………………………………………………………………………………………………………………. 63

5-1-2- اندیس درجه­بندی فیروزه (TGI) ………………………………………………………………………………………………………………63

5-1-2-1- سختی …………………………………………………………………………………………………………………………………………………… 64

5-1-2-2- رنگ ………………………………………………………………………………………………………………………………………………………. 64

5-1-2-3- پاکی ……………………………………………………………………………………………………………………………………………………… 65

5-1-2-4- طرح زمینه……………………………………………………………………………………………………………………………………………. 65

5-1-2-5- ترکیب فیروزه ……………………………………………………………………………………………………………………………………….. 66

5-1-2-6- بهسازی­شده ………………………………………………………………………………………………………………………………………….. 66

5-1-2-7-تراش ………………………………………………………………………………………………………………………………………………………. 67

5-1-2-8- اندازه …………………………………………………………………………………………………………………………………………………….. 67

5-2- ارزش­گذاری نهایی فیروزه ……………………………………………………………………………………………………………………………… 68

فصل ششم : نتیجه­گیری

6-1- مقدمه …………………………………………………………………………………………………………………………………………………………….. 70

6-2- شواهد رخداد فیروزه ……………………………………………………………………………………………………………………………………… 70

6-3- مطالعات میکروسکوپی …………………………………………………………………………………………………………………………………… 71

6-4- مطالعات زمین شیمیایی ……………………………………………………………………………………………………………………………….. 71

6-4-1- نتایچ پراش پرتو X …………………………………………………………………………………………………………………………………… 71

6-4-2- نتایج میکروسکوپ الکترونی روبشی (SEM)………………………………………………………………………………………….. 71

6-4-3- نتایج طیف سنجی جرمی پلاسمای جفت دیده القائی (ICP-MS)………………………………………………………. 72

6-4-3-1- نتایج حاصل از بررسی عناصر فرعی …………………………………………………………………………………………………….. 72

6-4-3-2- نتایج حاصل از بررسی عناصر کمیاب خاکی ……………………………………………………………………………………….. 72

6-4-3-3- شناسایی سنگ میزبان و جایگاه تکتونیکی …………………………………………………………………………………………. 72

6-5- شاخص درجه­بندی فیروزه (TGI) ……………………………………………………………………………………………………………….. 73

6-6- پیشنهادات ……………………………………………………………………………………………………………………………………………………… 73

منابع …………………………………………………………………………………………………………………………………………………………………………. 74

پیوست ……………………………………………………………………………………………………………………………………………………………………… 79

 

فهرست جداول

عنوان                                                                صفحه

جدول 1-1: خصوصیات فیزیکی فیروزه …………………………………………………………………………………………………………………….. 4

جدول 1-2: خصوصیات نوری فیروزه ………………………………………………………………………………………………………………………… 4

جدول 1-3: کانی­های گروه فیروزه ……………………………………………………………………………………………………………………………. 5

جدول 1-4: خصوصیات فیزیکی فیروزه و کانی­های شبه فیروزه …………………………………………………………………………… 11

جدول 1-5: مقایسه کلی فیروزه در ایران، مصر، ایالات متحده و چین …………………………………………………………………. 16

جدول 1-6: میزان صادرات فیروزه ایران و بیشترین کشورهای صادر شده از سال 1384 تا 139 ………………………. 18

جدول 3-1: نتایج آنالیز نمونه­های فیروزه به روشXRD براساس رنگ فیروزه ……………………………………………………. 48

جدول4-1: درصد فراوانی عناصر اصلی فیروزه آبی و کانی­های همراه …………………………………………………………………… 53

جدول4-2: درصد فراوانی عناصر اصلی فیروزه سبز و کانی­های همراه ………………………………………………………………….. 54

جدول 4-3: درصد فراوانی عناصر اصلی در فیروزه سبز – آبی و کانی­های همراه ………………………………………………… 54

جدول 5-2: امتیاز دهی سختی فیروزه …………………………………………………………………………………………………………………… 64

جدول 5-2: امتیاز دهی رنگ فیروزه ………………………………………………………………………………………………………………………. 64

جدول 5-3: امتیازدهی براساس پاکی …………………………………………………………………………………………………………………….. 65

جدول 5-4: امتیاز دهی براساس طرح زمینه ………………………………………………………………………………………………………….. 65

جدول 5-5: امتیاز دهی براساس ترکیب سنگ فیروزه …………………………………………………………………………………………… 66

جدول 5-6: امتیازدهی براساس بهسازی شده ………………………………………………………………………………………………………… 66

جدول 5-7: امتیازدهی براساس تراش ……………………………………………………………………………………………………………………. 67

جدول5-8: امتیازدهی براساس اندازه فیروزه ………………………………………………………………………………………………………….. 67

جدول5-9: ارزش­گذاری فیروزه براساس اندیس(TGI)…………………………………………………………………………………………… 67

جدول6-1: ارزیابی نهایی  فیروزه براساس اندیس TGI………………………………………………………………………………………………. 72

 

فهرست تصاویر

 

عنوان                                                                                                                                                               صفحه

شکل 1-1: ساختار یکایاخته فیروزه ……………………………………………………………………………………………………………………………. 3

شکل 1-2: الف ) فیروزه عجمی ، ب) فیروزه شجری …………………………………………………………………………………………………. 6

شکل 1-3: الف ) هاولیت رنگ شده ب) آدونتولیت ………………………………………………………………………………………………… 10

شکل 1-4: الف)  فیروزه مصر ب) فیروزه چین ………………………………………………………………………………………………………… 14

شکل1-5: الف) فیروزه معادن الف)Cerrillosب)Ajaxج)Bisbee د) Sleeping beauty……………………………. 15

شکل 2-1: راه­های دسترسی به منطقه …………………………………………………………………………………………………………………….. 21

شکل 2-2:الف) نمایی از محدوده معدن باغواز دید شمال ب) نمایی از تونل فروریخته  معدن باغو ………………….. 28

شکل 2-3: الف ) نمایی از دایک داسیت پورفیریک قطع کننده واحد های سنگ های نفوذی در منطقه که در

 اطراف آن فیروزه یافت می شود . ب) نمایی نزدیک از همان دایک ………………………………………………………. 29

شکل 2-4: نمائی از دایک داسیت پورفیریک که در مجاورت گرانودیوریت تزریق شده است …………………………………. 31

شکل 2-5: نمایی از فیروزه تشکیل شده در مجاورت دایک داسیت پورفیریک ………………………………………………………. 32

شکل 3-1: ارتوز در نور PPL……………………………………………………………………………………………………………………………………. 40

شکل 3-2:پیریتالف- نور PPL ب- نورXPL……………………………………………………………………………………………………….. 42

شکل 3-3:الف ) طلا در پیریت ب)اثر پیریت شکل­دار در نور PPL………………………………………………………………………. 42

شکل 3-4: پیریتالف – نور XPL، ب- نور PPL………………………………………………………………………………………………… 43

شکل 3-5: کوارتز به همراه اکسید آهن الف – نور PPL ، ب- نور XPL ………………………………………………………………. 43

شکل 3-6:هماتیت تیغه­ای در تورمالین الف – نور PPL ، ب- نور XPL……………………………………………………………….44

شکل 3-7: تورمالین شعاعی الف – نور PPL ، ب- نور XPL ……………………………………………………………………………….. 44

شکل 3-8: فیروزه همراه با دگرسانی سرسیتی الف  نور XPL ، ب- نور PPL……………………………………………………….. 45

شکل 3-9: آپاتیت الف – نورXPL ب- نور PPL………………………………………………………………………………………………… 46

شکل 3-10: پلاژیوکلاز سرسیتی شدهالف – نور XPL ، ب- نورPPL………………………………………………………………….. 46

شکل 3-11: تورمالین اکسید شدهالف – نور XPL، ب- نور PPL……………………………………………………………………… 47

شکل 4-1: نقطه P1وP2در نمونه فیروزه آبی آنالیز شده توسط SEM………………………………………………………………. 52

شکل 4-2: نقطه P3و P4در نمونه فیروزه آبی آنالیز شده توسط SEM………………………………………………………………. 53

شکل 4-3: نقطه P1،P2 وP3در نمونه فیروزه سبز آنالیز شده توسط SEM…………………………………………………….. 53

شکل 4-4: نقطه P1و P2در نمونه فیروزه سبز –آبی آنالیز شده توسط SEM ……………………………………………………. 53

 

 

فهرست نمودارها

 

عنوان                                                                                                                                             صفحه

نمودار1-1: میزان صادرات فیروزه از 1384 تا 1394 …………………………………………………………………………………………….. 18

نمودار3-1: طیف آنالیز نیمه کمی XRD نمونه B(G-B)…………………………………………………………………………………… 48

نمودار3-2: طیف آنالیز نیمه کمی XRD نمونه B(DB) …………………………………………………………………………………….. 48

نمودار3-3: طیف آنالیز نیمه کمی XRD نمونهB(LB)…………………………………………………………………………………….. 49

نمودار3-4: طیف آنالیز نیمه کمی XRDنمونه B(G)……………………………………………………………………………………….. 49

نمودار 4-5: نمودار عنکبوتی عناصر فرعی در سه نوع فیروزه و یک نوع نمونه سنگ میزبان هنجار شده با

داده­های تامپسون (1982) …………………………………………………………………………………………………………………. 55

نمودار 4-6: نمودار عنکبوتی عناصر کمیاب خاکی سه نمونه فیروزه و یک نمونه سنگ میزبان هنجار شده با کندریت C1 براساس داده­های واکیتا و همکاران (1984) ………………………………………………………………… 58

نمودار4-7: رده­بندی شیمیایی نمونه­های فیروزه باغو. الف) نمودارTAS((Cox et al., 1979Wilson,1989))

و قرارگیری سنگ­ها در محدوده داسیت (ب) نمودار log (Zr/TiO2)- SiO2اقتباس از (Winchester andFloyd , 1977) و قرار گیری نمونه­ها در محدوده داسیت – ریوداسیت ……….. 59

نمودار4-8: نمودار A/NK و A/CNK(Maniar and Piccoli,. 1989) برای تعیین درجه سیرشدگی ماگما

 از آلومینیم و قرار گیری نمونه­ها رد محدوده پرآلومینیمی …………………………………………………………………. 60

نمودار 4-9: نمودار مجموع قلیایی­ها در مقابل سیلیس برای تعیین ماهیت کلسیمی – قلیایی سنگ میزبان

فیرزوه (Irvine and Baragar , 1971)…………………………………………………………………………………………… 60

نمودار4-10: الف) نمودار تعیین جایگاه زمین­ساختی(Y+Nb)-Rb(Pearce et al,. 1984)و قرار گیری

 نمونه­ها در محدوده همزمان با برخورد. ب) نمودار R1-R2 (De la Roche et al,. 1980)

براساس مطالعات (Batchelor and Bowden,. 1985)  و قرار گیری نمونه­ها در محدوده

ماگماهای همزمان با تصادم و پس از تصادم ………………………………………………………………………………………. 61

نمودار4-11: نمودار شاخص دگرسانی و قرار گیری نمونه­ها در محدود کلریت-پیریت و ریولیت – داسیت به

سمت دگرسانی سرسیتی.(Large et al,. 2001) و (Khalifa et al,. 2011)…………………………….. 61

168 دیدگاه برای دانلود پروژه: زمین­شناسی، کانی­شناسی، ژئوشیمی و ارزیابی کانی­های گروه فیروزه در معدن باغو -دامغان و مقایسه آن با سایر فیروزه­ها

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